The colours Ancestry have given each of their population groups in Chromosome Painter don't seem to be fixed, which with 1500+ of them would be hard to do anyway. So, assuming they are picked just for your picture, to make it clearer, it's hard to see why they use such similar colours.
Fortunately there is a way to separate them: click on the names in the legend panel on the left and the colours will be turned on and off (greyed) accordingly.
I would also recommend looking at the ranges given for the groups' probabilities (or revisiting this). Click on each "ethnicity region" in the Ethnicity Estimate panel, to get the range. I think some here are believing too much of Ancestry's claims for this whole ethnicity thing, which is based on rather questionable assumptions, and seeing the ranges may calm that down a bit.
The numbers can still be a bit odd, of course. My 50% Scottish (all on my Dad's side) has a range of 34-50% - so they've picked a best estimate at one end of that range, for some reason. My England & Northwestern Europe figure of 43% becomes 35-56%, which looks plausible enough. But note that the small numbers have ranges almost that big, leading to a higher level of doubt for them.
So, I was a bit puzzled to see 6% Norwegian, and 1% Sweden & Denmark. Now I know the "Danes" who came to East Anglia were not all from Denmark, but I thought more were than were from Norway. The ranges I'm given for those are 0-15% Norway and 0-12% Sweden & Denmark. So anything or nothing, really.